In this work, we investigate the time-like pion form factor from lattice QCD in the isosymmetric limit, a quantity that plays an important role in understanding hadron physics with substantial phenomenological applications. This observable can be calculated in the elastic region using the finite-volume approach, up to the first (four-particle) open channel. With the goal of accessing the exclusive two-pion form factor in the inelastic region, starting from a three-point correlator involving the vector current and two (temporally-displaced) pion interpolating operators, we examine the associated underlying spectral density and calculate the form factor using a formalism based on the LSZ reduction. A preliminary analysis on one ensemble generated by the RBC/UKQCD collaboration using domain-wall fermions is presented.