In the potential model frame work, we study the S-wave molecular like structure of the Hexaquark systems which consist baryon-baryon or baryon-antibaryon as a constituents. The mass spectra of the $\Sigma_{c}-\Sigma_{c}$ and $\Sigma_{c}-\overline{\Sigma_{c}}$ are predicted. By taking the deuteron as an approximation for our model calculation, the S-wave mass spectra of the molecular Hexaquark system are extracted. The One Boson Exchange Potential plus screen Yukawa-like potential is being used for the inter baryon-baryon(antibaryon) interaction. The calculated mass spectra with possible quantum numbers are presented here.