We present a calculation of the pion form factor using overlap fermions on 2+1-flavor domain-wall configurations on a $24^3\times 64$ lattice with $a=0.11 \, {\rm{fm}}$ and on a $32^3 \times 64$ lattice with $a=0.143 \, {\rm{fm}}$ generated by the RBC/UKQCD collaboration. Using the multi-mass algorithm, a simulation has been done with various valence quark masses with a range of space-like $Q^2$ from 0.0 to 0.6 ${\rm{GeV^2}}$.