The purpose of this work is to do a systematic feasibility study of measuring in backward region deeply virtual Compton scattering on the pion in Sullivan processes in the framework of collinear QCD factorization where pion to photon transition distribution amplitudes (TDAs) describe the photon content of the $\pi$ meson. Our approach employs TDAs based on the overlap of light front wave functions, using a previously developed pion light-front wave function and deriving a consistent model for the light front wave functions of the photon. This work is expected to lead us to an estimate of the cross-sections that could be measured in the future U.S. and China's electron-ion colliders. It will also provide a comparison with the forward Sullivan DVCS case, which gives access to pion GPDs and for which a strong signal is expected.